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alt="二氧化氯在循環冷卻水中應用"/><span>新聞資訊</span></p> <div class="div_list"> <div class="list_con"><a href="/news/gongsixinwen/" title="公司新聞" rel="nofollow">公司新聞</a></div> <div class="list_con"><a href="/news/xingyezixun/" title="行業資訊" rel="nofollow">行業資訊</a></div> </div> </div> </div> </div>   <div class="ny_right"> <div class="ny_right_content"> <div class="article_title"><h1>二氧化氯在循環冷卻水中應用</h1></div> <div class="artdet">發布時間：2020-08-28</div> <div id="news_con"> <div> 1、概述：<br /> 　　<br /> 　　循環冷卻水系統的環境，為微生物繁殖提供了優越的條件。適宜微生物滋長的水溫25℃～40℃<span class="fbt">佛山防腐木售貨車</span>，飽和的溶解氧，適中的PH值，豐富的營養源，濃縮倍數提高，導致含鹽量的增加，工藝介質泄漏，以及傾向于采用堿性有機磷系配方作為水質穩定劑，充足的陽光等都為循環冷卻水微生物滋長營造一個理想的環境。以這些微生物為主體，混雜泥砂、無機物和塵土等，形成生物粘泥附著與堆積<span class="fbt">佛山防腐木售貨車</span>，因而產生粘泥故障，引起設備、管道的局部腐蝕、堵塞等不良問題，降低換熱器的熱交換效率，甚至使管道穿孔，設備損壞。因此，必須在循環冷卻水中投加殺菌劑，以控制微生物的生長。<br /> 　　殺菌劑按化學成分可分為無機殺菌劑和有機殺菌劑兩種；按殺菌劑的機理可分為氧化型殺菌劑和非氧化型殺菌劑兩種，其中二氧化氯殺菌劑是國內循環水行業廣泛推廣應用的氧化型無機殺菌劑。<br /> 　　 2.二氧化氯殺菌劑的特點：<br /> 　　 2.1、二氧化氯的物化性質：<br /> 　　二氧化氯分子式為ClO2，是一種隨濃度升高顏色由黃綠色到橙色的氣體，具有與氯氣相似的刺激性氣味。氣體密度為3.09g/l。純二氧化氯的液體與氣體性質極不穩定，在空氣中二氧化氯的濃度超過10％時就會有很高的爆炸性，因此二氧化氯不能像液氯那樣裝瓶運輸，必須在現場現制現用。二氧化氯易溶于水，溶解度約為氯氣的5倍。二氧化氯溶液濃度在10g/l以下時，基本沒有爆炸的危險。<br /> 　　二氧化氯的化學性質非?；顫?，一般在酸性條件下具有很強的氧化性，其氧化能力僅次于臭氧?？裳趸卸喾N無機物和有機物，主要反應如下：<br /> 　　與無機物反應<br /> 　　2ClO2+5Mn2++6 H2O=5MnO2+2Cl-+12H+<br /> 　　ClO2+5Fe(HCO3)2+13H2O=5Fe(OH)3+10CO32-+Cl-+21H+<br /> 　?、谂c有機物反應<br /> 　　ClO2+ 飽和烴→酸<br /> 　　烯烴→酮、環氧化物、醇<br /> 　　醛→酸<br /> 　　酮→醇<br /> 　　一元胺、二元胺→緩慢反應<br /> 　　三元胺→反應較易，導致C-N鍵斷裂，生成醛<br /> 　　醇→羧酸<br /> 　　分解反應<br /> 　　二氧化氯在水中以純粹的溶解氣體形式存在，不發生水解反應。但二氧化氯的水溶液在較高溫度與光照下，會生成ClO2與ClO3-。反應式如下：<br /> 　　2ClO2+hv+ H2O= HClO3+HCL+2O*<br /> 　　 2.2.二氧化氯的殺菌性能：<br /> 　?、贇⒕?，作用快，藥效時間長。<br /> 　　<br /> 　　二氧化氯和液氯消毒效果比較<br /> 　　消毒劑效果 ClO2<br /> 　　（3.0mg/l）液氯<br /> 　　(3.0mg/l)<br /> 　　細菌總數消毒前 102 240 540 890 1400 1710 102 240 540 890 1400 1710<br /> 　　消毒后 3，2，3，1，3，4 1，1<span class="fbt">佛山防腐木售貨車</span>，4，2，12，X<br /> 　　大腸菌群消毒前 13，38，52，60，92 13，38，52，60<span class="fbt">佛山防腐木售貨車</span>，92<br /> 　　消毒后＜3, ＜3, ＜3, ＜3, ＜3 ＜3, ＜3, ＜3, ＜3, ＜3<br /> 　　<br /> 　　<br /> 　　就殺菌效果來說，臭氧＞二氧化氯＞氯＞氯胺；就穩定性來看，氯胺＞二氧化氯＞氯＞臭氧。綜合而言，二氧化氯的殺菌性能*佳。<br /> 　　二氧化氯不僅能夠殺死一般的細菌，而且對真菌、病毒、孢子等微生物都有極強的殺滅作用。<br /> 　　廣譜，對異養菌、鐵細菌、硫酸鹽還原菌等均有較高的殺菌效率。一般只需0.5mg/L即可快速殺死和抑制細菌生產，1mg/L以上殺滅細菌的時間只需5min。而且可以單獨長期使用而不發生抗藥性。<br /> 　　可在較寬的PH值范圍（6-9）使用<span class="fbt">佛山防腐木售貨車</span>，在高PH值的冷卻水中仍具有較高的殺菌效果。二氧化氯在水中以溶解的氣體存在而不與水發生反應，它的分解產物為HCLO和 “O”(新生態氧)，既具有雙重氧化作用，又不受PH值影響。PH為8.5時，二氧化氯保持相同的效率，而氯氣則需要5倍殺菌時間，殺菌率降至44％～ 45％。<br /> 　　二氧化氯不僅能強力殺菌，而且控制藻類和粘泥也十分有效。CLO2對苯環有一定的親和性，能使苯環發生變化。葉綠素中的吡咯環與苯環非常類似，CLO2同樣能作用于吡咯環。因此，二氧化氯氧化葉綠素，藻類新陳代謝終止，使得蛋白質的合成中斷<span class="fbt">佛山防腐木售貨車</span>，導致其死亡。達到控制菌藻的目的。<br /> 　　二氧化氯殺生維持時間長。實驗表明1mg/l的二氧化氯48h后仍能維持殺生率95%以上<span class="fbt">佛山防腐木售貨車</span>，而氯氣一般超過12h后就無殺生效果。<br /> 　　二氧化氯降解有機物適應于環保的要求。氯降解有機物是發生氯代反應，伴隨有毒的致癌致畸的氯代有機物產生，而二氧化氯是發生氧化反應，使有機物轉化為無機物，降解產物無毒害作用，不污染環境。<br /> 　　二氧化氯不與氨和氨基化合物反應，殺菌效果和用量不受氨存在的影響。<br /> 　　少量投加二氧化氯殺菌滅藻<span class="fbt">佛山防腐木售貨車</span>，對金屬設備基本無腐蝕。二氧化氯對金屬設備腐蝕實驗表明：投加80~120mg/L的二氧化氯對不銹鋼和銅基本無腐蝕，投加20~80ml/L的二氧化氯對碳鋼基本無腐蝕，因此，二氧化氯在循環水系統中投加量低于80mg/L時，不會對設備造成腐蝕。<br /> 　　 3.二氧化氯在工業循環冷卻水處理中的應用：<br /> 　　循環水系統二氧化氯的投加一般依托二氧化氯發生器來完成。二氧化氯發生器是一種現場生產二氧化氯的設備，從原理上分為兩大類：電解法和化學法。<br /> 　　電解法生產二氧化氯是根據電極反應原理，電解食鹽溶液產生ClO2、Cl2、O3及H2O2混合氣體；化學法生產二氧化氯是以氯酸鈉（NaClO3）或次氯酸鈉（NaClO2）為原料經化學反應來制取ClO2的。以NaClO2為原料生產二氧化氯的基本反應式為：<br /> 　　 5NaClO2+4HCl＝ClO2+5NaCl+2H2O </div> </div> <div class='bsz'><dt id='mXlAd'><div id='mXlAd'><abbr id='mXlAd'><strike id='mXlAd'></strike></abbr></div></dt><pre id='mXlAd'><dl id='mXlAd'></dl></pre><small id='mXlAd'><acronym id='mXlAd'><i id='mXlAd'><label id='mXlAd'><kbd id='mXlAd'><form id='mXlAd'><div id='mXlAd'><strike id='mXlAd'></strike></div></form></kbd></label></i></acronym><bdo id='mXlAd'></bdo><strike id='mXlAd'><table id='mXlAd'></table></strike></small><option id='mXlAd'></option><th id='mXlAd'><del id='mXlAd'></del></th><blockquote id='mXlAd'></blockquote><acronym id='mXlAd'><dd 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